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Posted Date: 01 Aug 2009 Posted By: Sunil Reddy Member Level: Platinum
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2009 Jawaharlal Nehru Technological University Jntu Hyderabad, Code No: 07A4BS03 Set No.4 II B.Tech II Semester Regular Examinations, May 2009 ORGANIC CHEMISTRY (Chemical Engineering) Question paper
Code No: 07A4BS03 Set No. 4 II B.Tech II Semester Regular Examinations, May 2009 ORGANIC CHEMISTRY (Chemical Engineering) Time: 3 hours Max Marks: 80 Answer any FIVE Questions All Questions carry equal marks ? ? ? ? ? 1. (a) Differentiate between inductive effect and resonance effects giving examples (b) Explain why ammonia is a weaker base than diethylamine ? [8+8] 2. (a) What are electrophiles? Explain the different types giving examples. (b) Explain why electrophilic substitution reactions take place in benzene? [8+8] 3. (a) Discuss the reaction between acetone and p-dimethylaminobenzaldehyde in the presence of aq.ethanolic NaOH. (b) Outline a laboratory method for the preparation of Cinnamic acid? [8+8] 4. (a) Describe any two methods for radical generation. (b) Give one example for neutral radical, cation radical and anion radical. (c) Describe the thermal halogenation of ethane. [6+6+4] 5. (a) What is geometrical isomerism in organic compounds due to? (b) Explain the E-Z system of nomenclature for geometrical isomers giving exam- ples. [10+6] 6. Describe the preparation, properties and use of: (a) Teflon and (b) Nylon. [8+8] 7. Formulate the following reactions and give explanation for the formation of respec- tive products:- (a) Furfuraldehyde is treated with Conc. HNO3 at RT (b) 2-Methylquinoline is heated with benzaldehyde at 1500C (c) Pyrrole is treated at room temperature with pyridine SO3 complex (d) Thiophene is heated with a mixture of KOH and CHCl3 followed by hydrolysis. [4×4] 8. (a) If a compound does not show absorption in the UV region of electromagnetic spectrum, can it exhibit the property of colour? (b) Draw the resonance structures of Bismark - Brown - R.
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