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Posted Date: 03 Aug 2009 Posted By: Gulshan Kumar Member Level: Silver
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2008 ICSE Kurukshetra University A.M.I.E.T.E Information Technology Chemistry paper Question paper
Section – I (40 Marks)
Answer all the questions from this section
Question – 1.
(a) Select the correct alternative from the given bracket to make the statement true :
(i) A solution which on heating with CaCO3, we get the CO2 gas is _________ [conc. H2SO4 / dil. HCl / dil. H2SO4].
(ii) A solution which is used to distinguish an ammonium salt from a sodium salt is ______ [CuCl2 soln / NH4OH / dil. H2SO4 / AgNO3 soln.]
(iii) The pH of blood is 7.4, of saliva is 6.5 and a dil. acid 4.5. A solution which is alkaline is ____________ [dil. acid / saliva / blood].
(iv) Decomposition of ________ [NaCl / NaHCO3 / NaNO3] by dil. H2SO4 an unstable acid is formed.
(v) A metal which reacts with an alkali to liberate hydrogen is _______ [iron / copper / aluminium].
(b) Give balanced equations for the conversion of the following :-
(i) An alkane to an alcohol (ii) An alkene to an alkane (iii) An alkyne to an alkene
(iv) An alcohol to an alkene (v) An aldehyde to an acid.
(c) Give reasons for the following :
(i) Hydrogen sulphide is used as an analytical reagent in the laboratory.
(ii) Conc. sulphuric acid is used in the laboratory preparation of iodine from hydrogen iodide.
(iii) To distinguish between dil. H2SO4 and dil. HNO3, barium chloride can be used.
(iv) The gas obtained when zinc reacts with dil. H2SO4 or conc. H2SO4 are different.
(v) H2S and SO2 decolourises acidified KMnO4 solution, even then the two gases can be distinguished with the same.
(d) Fill in the blanks from the given alternatives in the brackets :
(i) Lead nitrate is a / an ___________ [acid / normal] salt of nitric acid.
(ii) When H2S reacts with Dil. HNO3, the oxidized product obtained is ________ [sulphur / sulphur dioxide / sulphuric acid]
(iii) A nitrate on heating melts and liberates only one neutral gas is ________ [lead nitrate / sodium nitrate / silver nitrate / calcium nitrate].
(iv) A mineral acid obtained from conc. nitric acid on reaction with a non-metal is ________ [carbonic acid / sulphuric acid / hydrochloric acid].
(v) The reaction of __________ [calcium oxide / calcium carbonate / calcium sulphate] with dilute nitric acid is an example of neutralization reaction.
(e) Choose the most probable substance from (A),(B),(C),(D) and (E) which need to be added to distinguish :
(i) Ammonia and sulphur dioxide gas (ii) Ammonium sulphate and ammonium chloride
(iii) liquor ammonia and liquid ammonia (iv) Copper (II) oxide and copper (II) chloride
(v) Potassium sulphate and ammonium sulphate;
(A) conc. hydrochloric acid (B) Ammonia gas (C) Barium chloride (D) Phenolphthalein
(E) Sodium hydroxide.
(f) Choose the compounds from (A),(B),(C),(D) and (E) to match the description (i) to (v) given below :
(A) NH4Cl, (B) Ag(NH3)2Cl,(C) AgCl, (D) FeCl2, (E) PbCl2
(i) A soluble salt obtained on reaction of a metallic chloride with liquor ammonia.
(ii) A salt which is insoluble dilute nitric acid but soluble in ammonium hydroxide.
(iii) A salt obtained on reaction of an active metal with hydrogen chloride gas.
(iv) A salt obtained when a basic gas reacts with hydrogen chloride gas.
(v) A salt soluble in hot water but not in cold, obtained on heating an oxidizing agent with conc. HCl.
(g) Name a metal from the activity series which (i) forms an oxide on exposure to air, (ii) displaces hydrogen from steam, (iii) does not react with dilute HCl or H2SO4, (iv) forms an oxide and hydroxide soluble in water and (v) forms a nitrate which on thermal decomposition metal is left.
(h) Match the statements in (i) to (v) selecting from (A) to (J) given below :
(A) Anode, (B)Cathode, (C) Sucrose solution, (D) Cl1-, (E) Formic acid, (F) Ammonia, (G) Electrometallurgy, (H) Mg2+, (I) Electrorefining, (J) Sulphur dioxide :
(i) A compound which contains molecules only.
(ii) A compound which ionizes in solution but not in gaseous state.
(iii) An ion which accepts electrons from the cathode and is reduced to neutral atoms.
(iv) The electrode to which the cyanide ions of Na[Ag(CN)2] solution in water migrate during electrolysis.
(v) An application of electrolysis in which the anode does not generally diminish in its size.
Question – 2.
(a) Calculate the percentage of water of crystallization in hydrated copper sulphate [CuSO4.5H2O] [Cu = 63.5, S = 32, O = 16, H = 1] [Ans. 36.07%]
(b) Following data were obtained from a compound : C = 57.82%, O = 38.58% and rest hydrogen. Its vapour density is 83. Find its empirical and molecular formula. [C = 12, O = 16, H = 1] [Ans. C4H3O2 and C8H6O4]
? ?
(c) 2KClO3 ? 2KCl + 3O2 ; C + O2 ? CO2
using the above equation, calculate the amount of KClO3, which on being heated decomposes to give some volume of O2, which is the volume required for the combustion of 24 g of carbon. [K = 39, Cl = 35.5, O = 16, C = 12] [Ans. 163.33 g.]
Question – 3.
(a) Explain the action of NaOH on the following with suitable chemical equations :
Zn, PbO, ZnO, Al2O3 and Zn(OH)2.
(b) Define the following with suitable example :
Water of crystalisation ; Deliquescence ; Efflorescence ; Electrovalent and Covalent bonds.
Question – 4.
(a) Write the electron dot formula of the following compounds :
Water, Ammonia, Methane, Oxygen molecule and Carbon tetrachloride.
(b) With reference to the period 3 of the periodic table – write
(i) The type of bonding in element whose electronic configuration is 2, 8, 7.
(ii) The formula of the chloride of element whose electronic configuration is 2, 8, 4.
(iii) The nature of the oxide of the alkaline earth metal in this period.
(iv) The number of electrons in the penultimate shell of the element whose valency is – 1.
(v) The electronic configuration of the element whose hodroxide is a weak base.
Question – 5.
(a) From the list of substance given below choose the pair required to prepare the salts (i) to (v) in the laboratory and write down the relevant equations. The substances are :
Copper, Lead, Sodium, Zinc, Potassium, Copper oxide, Lead carbonate, sodium carbonate solution, Dilute hydrochloric acid, Dilute nitric acid, and dilute sulphuric acid.
(i) Zinc sulphate ; (ii) Copper sulphate ; (iii) Sodium sulphate ; (iv) Lead sulphate and
(v) potassium sulphate.
(b) Name the ions formed when – HCl ; HNO3 ; H2SO4 ; CH3COOH ; NaOH ; NaCl ; Na2CO3 ; H3PO4 ; KOH and NH4OH ionizes in aqueous solution.
Question – 6.
(a) ‘Iron is electroplated with silver’. (i) Define electroplating. (ii) Draw diagram for electroplating. (iii) State two reasons for electroplating. (iv) Why iron is not placed at the anode and silver at the cathode during electroplating ?
(b) Give one use with reason of aluminium in (i) metallic, (ii) powder, (iii) foil, (iv) wire and (v) alloyed form.
Question – 7.
(a) Name three chemical products manufactured from nitric acid. Give two general uses of HNO3.
(b) Starting from H2S how would you obtain Sulphur using – (i) chlorine, (ii) SO2, (iii) conc. H2SO4, (iv) oxygen and (v) nitric acid.
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