It is really good that you want to pursue UGC NET, because UGC NET is to determine The Eligibility of Indians for Assistant Professor only or Junior Research Fellowship and Eligibility for Assistant Professor.
If you clear UGC NET then you can apply for the position of Lecturer/Assistant Professor in Universities and Colleges located anywhere across India. You Will also eligible for Junior Research Fellowship. the fellowship is upgraded to SRF (NET) and the stipend is increased to Rs. 28,000/- per month for the 3rdand subsequent years.
If you have to face transfer, then you can apply for a the position of Lecturer/Assistant at new place in new college.