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JNTU 2007-2008 1ST YEAR B.Tech -PHYSICAL CHEMISTRY
Posted Date: 09 Dec 2007 Resource Type: Articles/Knowledge Sharing Category: Syllabus
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Posted By: Sri Member Level: Gold
Rating:  Points: 1
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JAWAHARLAL NEHRU TECHNOLOGICAL UNIVERSITY
HYDERABAD
I Year B.Tech. Ch.E T P C
2+1* 0 4
PHYSICAL CHEMISTRY
UNIT I: Distribution Law:
Distribution Law – Nernst Distribution Law – Distribution Coefficient – Explanation and Limitations of Distribution Law - Modification of Distribution Law – Determination of Equilibrium Constant from Distribution Coefficient – Applications of Distribution Law.
UNIT II: Phase Rule:
Phase Rule – Terms involved in Phase Rule – Types of Liquids – Derivation of Phase Rule – Phase Diagrams of One Component (Water and Sulphur system), Two Component System – Eutectic Point (Lead Silver System) and three component system. Applications of Phase Rule.
UNIT III: Chemical Kinetics:
Introduction to Chemical Kinetics – Theories of Reaction Rates – Collision Theory – Modified Collision Theory – Absolute Reaction Rate Theory (Transition State Theory) – Reaction between Ions – Influenece of Solvent (Double Sphere Activated Complex and Single Sphere Activated Complex) – Influence of Ionic Strength on the Rate of the Reactions - Chain Reactions – Hydrogen and Bromine, Hydrogen and Oxygen (Steady State Treatment) – Explosion Limits.
UNIT IV: Colloidal State:
Definition of Colloids, Classification of Colloids, Solids in liquids (sols) – Properties, kinetics, optical and Electrical; Stability of Colloids, Protective Action, Hardy – Schultz Law, Gold Number. Liquids in Liquids (Emulsions) – Types of Emulsions, Preparation , Emulsifier, Liquid in Solids (gels) – classification, Preparation and Properties, General Applications of Colloids.
UNIT V: Electrochemistry – I:
Ohms Law – Conductance – Specific Conductance – Equivalent Conductance – Molecular Conductance and its determination – Transport Number and its Determination – Kohlrauschs Law, its Application – Conductometric Titrations – Applications of Conductivity Measurements.
UNIT VI: Electrochemistry – II:
EMF; Galvanic cells, Spontaneity, Reversible & irreversible cells, Measurement of EMF, Standard Electrode potential, concentration cells, batteries, fuel cell, hydrogen oxygen fuel cell, photgalvanic cell, photovoltaic cells.
UNIT VII: Catalysis:
Homogeneous Catalysis – Catalysis by electron and group transfer in solution – Acid-Base Catalysis – Protolytic and Prototropic Mechanism, Enzyme Catalysis – Specificity – Examples – Influence of Concentration (Michaelis Constant) – Influence of pH – Influence of Temperature.
UNIT VIII: Voltammetry:
Principle of Micro electrolysis, polarization, Dropping Mercury Electrode, Polarograph, Half Wave Potential, IIlkovic Equation, Qualitative analysis and Quantitative analysis, Standard addition technique and Applications, amperometric titrations.
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