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JAWAHARLAL NEHRU TECHNOLOGICAL UNIVERSITY
HYDERABAD
II Year B. Tech. AE – II semester T P C
4+1 0 4
THERMODYNAMICS
Tables/Codes: Steam Tables and Mollier Chart, Refrigeration Tables should be supplied
UNIT – I
System, Control Volume, Surrounding, Boundaries, Universe, Types of Systems, Macroscopic and Microscopic viewpoints, Concept of Continuum, Thermodynamic Equilibrium, State, Property, Process, Cycle – Reversibility – Quasi – static Process, Irreversible Process, Causes of Irreversibility – Energy in State and in Transition, Types, Work and Heat, Point and Path function.
UNIT II
Zeroth Law of Thermodynamics – Concept of quality of Temperature – Principles of Thermometry – Reference Points – Const. Volume gas Thermometer – Scales of Temperature, Ideal Gas Scale – PMM I - Joule’s Experiments – First law of Thermodynamics – Corollaries – First law applied to a Process – applied to a flow system – Steady Flow Energy Equation.
UNIT – III
Limitations of the First Law – Thermal Reservoir, Heat Engine, Heat pump , Parameters of performance, Second Law of Thermodynamics, Kelvin-Planck and Clausius Statements and their Equivalence / Corollaries, PMM of Second kind, Carnot’s principle, Carnot cycle and its specialties, Thermodynamic scale of Temperature, Clausius Inequality, Entropy, Principle of Entropy Increase – Energy Equation, Availability and Irreversibility – Thermodynamic Potentials, Gibbs and Helmholtz Functions, Maxwell Relations – Elementary Treatment of the Third Law of Thermodynamics.
UNIT IV
Pure Substances, p-V-T- surfaces, T-S and h-s diagrams, Mollier Charts, Phase Transformations – Triple point at critical state properties during change of phase, Dryness Fraction – Clausius – Clapeyron Equation Property tables. Mollier charts – Various Thermodynamic processes and energy Transfer – Steam Calorimetry.
UNIT - V
Perfect Gas Laws – Equation of State, specific and Universal Gas constants – various Non-flow processes, properties, end states, Heat and Work Transfer, changes in Internal Energy – Throttling and Free Expansion Processes – Flow processes – Deviations from perfect Gas Model – Vander Waals Equation of State – Compressibility charts – variable specific Heats – Gas Tables
UNIT – VI
Mixtures of perfect Gases – Mole Fraction, Mass friction Gravimetric and volumetric Analysis – Dalton’s Law of partial pressure, Avogadro’s Laws of additive volumes – Mole fraction , Volume fraction and partial pressure, Equivalent Gas const. And Molecular Internal Energy, Enthalpy, sp. Heats and Entropy of Mixture of perfect Gases and Vapour, Atmospheric air - Psychrometric Properties – Dry bulb Temperature, Wet Bulb Temperature, Dew point Temperature, Thermodynamic Wet Bulb Temperature, Specific Humidity, Relative Humidity, saturated Air, Vapour pressure, Degree of saturation – Adiabatic Saturation , Carrier’s Equation – Psychrometric chart.
UNIT - VII
POWER CYCLES
Otto, Diesel, Dual Combustion cycles, Sterling Cycle, Atkinson Cycle, Ericcson Cycle, Lenoir Cycle – Description and representation on P–V and T-S diagram, Thermal Efficiency, Mean Effective Pressures on Air standard basis – comparison of Cycles.
UNIT VIII
REFRIGERATION CYCLES
Brayton and Rankine cycles – Performance Evaluation – combined cycles, Bell- Coleman cycle, Vapour compression cycle-performance Evaluation.
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