509126 [Elective IV] ( b ) : Elastomer Technology Teaching Scheme Examination Scheme Lectures : 3 Hrs/week Paper : 100 marks
Objectives: Elastomers are an important area of Material Science where polymeric materials are exclusively used. These materials find wide spread applications in automotive, aviation, marine, electrical industries. In this course the details pertaining to raw materials, formulations, processing, testing, applications have been presented. A sound understanding of these polymeric materials would equip the students for careers in rubber industry. Revision of basic concepts Rubber Elasticity: Physics of raw and vulcanized rubber. Kinetic and thermodynamics theory of rubber elasticity. Stress strain relationships for vulcanized rubber. Molecular basis for material to act as a rubber. Stages in raw rubber and latex rubber technology such as mastication, mixing and compounding and vulcanization. Study of various additives like peptizers, antioxidants, accelerators, activators, fillers, carbon black reinforcement, chords and fabrics, blowing agents, colorants, Processing aids like tackifiers, plasticizers, softeners, extender oils, their function, level of addition and stage of addition. Characterization of compounds, rheological behaviour of compounds, properties influenced by compounding ingredients. Processing of rubbers by extrusion, calendaring and injection moulding. Manufacturing techniques for products such as tyres, belts, hoses, foot wears, cellular products and cables. Manufacture of latex based products such as dipped goods, foams and threads. Testing of rubber products. Study of major elastomeric materials like natural rubber SBR, NBR, IIR, CR, BR, with respect to synthesis, compounding considerations, cure characteristics. Study of thermoplastic elastomers with respect to compounding, properties and applications. Vulcanization of rubbers: Vulcanization by Sulphur and by other methods. Chemical reactions, factors affecting rate of vulcanization. Determination of cure rate of rubbers. Testing and analysis of raw rubber, compounds and vulcanizates. Testing finished rubber products, test methods and fundamentals.
References : 1. Science and Technology of Rubbers, J.E.Mark, B.Ermas, F.R.Eirich,”Academic Press 1994 2. Rubber Processing Technology, Materials and Principles, J.Lwhite, Hanser Publishers 1995 3. W.Hofmann “Rubber Technology Handbook, Hanser Publishers 1989 4. Rubber Technology and Manufacture C.M.Blow, C.Hepburn, Butterworth Publishers 1985. 5. Thermoplastics Elastomers, N.R.Legge, G.Holden, H.E.Schroedar Hanser Publishers 1987. 6. Rubber Technology Handbook, C. Hoffman, Hanser Pub. 1989. 7. Synthetic Rubbers: Chemistry and Technology, D.C. Blackley,Applied Science Publisher,1983. Reference http://www.unipune.ernet.in/stud_info/Syllabi/Syllabus_2008.html
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